On contact with oxygen or water, both polonium monoxide and its related hydroxide (polonium(II) hydroxide, Po(OH)2) are oxidized quickly to Po(IV).[2]
References
12Holleman, Arnold Frederik; Wiberg, Egon (2001), Wiberg, Nils (ed.), Inorganic Chemistry, translated by Eagleson, Mary; Brewer, William, San Diego/Berlin: Academic Press/De Gruyter, p.594, ISBN0-12-352651-5