It was discovered in 1960 in Ajo, Arizona, United States, and was named after the Hia C-eḍ Oʼodham people (also known as the Sand Papago) who inhabit the area.[5] This location is the only papagoite source within the United States, while worldwide it is also found in South Africa and Namibia. It is associated with aurichalcite, shattuckite, ajoite and baryte in Arizona, and with quartz, native copper and ajoite in South Africa.[5] Its bright blue color is the mineral's most notable characteristic.