Iodyl fluoride
Iodyl fluoride
Names
IUPAC name
Fluoro(dioxo)-λ5 -iodane Iodine(V) fluoride dioxide
Identifiers
ChemSpider
InChI=1S/FIO2/c1-2(3)4
Key: FRYHXHDHQQGJSF-UHFFFAOYSA-N
Properties
IO2 F
Molar mass g·mol−1
Appearance
colorless crystals
Density 4.982 g/cm3
Melting point 200 °C (392 °F; 473 K)
Reacts with water
Related compounds
Related compounds
Except where otherwise noted, data are given for materials in their
standard state (at 25
°C [77
°F], 100
kPa).
Chemical compound
Iodyl fluoride is an inorganic compound of iodine , fluorine , and oxygen with the chemical formula IO2 F . It is in the form of colorless crystals. Iodyl fluoride features iodine in the oxidation state of +5. The compound was initially synthesized in 1951.[ 1]
References
1 2 3 Aynsley, E. E.; Nichols, R.; Robinson, P. L. (1 January 1953). "126. Reactions of iodine pentafluoride with inorganic substances. Iodine oxytrifluoride and iodyl fluoride" Journal of the Chemical Society 623– 626. doi :10.1039/JR9530000623 . ISSN 0368-1769 . Retrieved 24 May 2023 . ↑ Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry Academic Press . p. 468. ISBN 978-0-12-352651-9 . Retrieved 24 May 2023 . ↑ Minkwitz, Rolf; Berkei, Michael; Ludwig, Ralf (1 December 2001). "Crystal Structure of IO2F" Inorganic Chemistry 40 (25): 6493– 6495. doi :10.1021/ic0105462 . ISSN 0020-1669 . PMID 11720506 . Retrieved 24 May 2023 . ↑ Haynes, William M. (4 June 2014). CRC Handbook of Chemistry and Physics CRC Press . p. 4-67. ISBN 978-1-4822-0868-9 . Retrieved 24 May 2023 . ↑ Schmeisser, M.; Brändle, K. (1 January 1963). "Oxides and Oxyfluorides of the Halogens" Advances in Inorganic Chemistry and Radiochemistry . 5 . Academic Press: 41– 89. doi :10.1016/S0065-2792(08)60152-1 . ISBN 9780120236053 . Retrieved 24 May 2023 . ↑ Advances in Inorganic Chemistry and Radiochemistry Academic Press . 1 January 1963. ISBN 978-0-08-057854-5 . Retrieved 24 May 2023 .
Iodine(−I) Iodine(I) Iodine(II) Iodine(III) Iodine(IV) Iodine(V) Iodine(VII)
Salts and covalent derivatives of the
fluoride ion
PF− 6 , AsF− 6 , SbF− 6 compoundsAlF2− 5 , AlF3− 6 compoundschlorides, bromides, iodides SiF2− 6 , GeF2− 6 compoundsOxyfluorides Organofluorides with transition metal, nitric acids bifluorides thionyl, phosphoryl,
