Baloyi made his professional debut in 1993. He joined league rivals Mamelodi Sundowns in 2004 after playing for Kaizer Chiefs for over a decade. He is commonly nicknamed "Spiderman".
Baloyi's wife, Phungi, is a breast cancer survivor. She was one of the mourners at the funeral of the wife of Lucas Radebe, Feziwe, who were handed pink ribbons to wear to raise awareness of cancer. He has a son named Kgosi.[5]