Isotopes of francium
Francium (87 Fr) has no stable isotopes , so a standard atomic weight cannot be given. Its most stable isotope is 223 Fr with a half-life of 22 minutes, occurring in trace quantities in nature as an intermediate decay product of 235 U .
Of elements whose most stable isotopes have been identified with certainty, francium is the most unstable, though astatine is the rarest in nature due to its naturally occurring isotopes having even shorter half-lives and even smaller branching ratios.
The elements with atomic number of 106 (seaborgium ) or greater have their longest known half-life of any isotope shorter than that of francium, but as those elements have only isotopes on the proton-rich side of beta stability discovered, there is a strong possibility that undiscovered isotopes of these elements will have longer half-lives that could exceed that of francium-223.
List of isotopes
Nuclide[ n 1]
Historic name
Z
N
Isotopic mass (Da ) [ 2] [ n 2] [ n 3]
Discovery year[ 3] [ 4]
Half-life [ 1] [ n 4]
Decay mode [ 1] [ n 5]
Daughter isotope
Spin andparity [ 1] [ n 6] [ n 4]
Isotopic abundance
Excitation energy[ n 4]
197 Fr
87
110
197.01101(6)
2013
2.3(19) ms
α
193 At
(7/2−)
198 Fr
87
111
198.01028(3)
2013
15(3) ms
α
194 At
3+#
198m Fr[ n 7]
0(50) keV
2013
1.1(7) ms
α
194 At
(10−)
199 Fr
87
112
199.007269(15)
1999
6.6(22) ms
α
195 At
1/2+#
199m1 Fr
45(13) keV
2013
6.5(9) ms
α
195 At
7/2−#
199m2 Fr
250(50)# keV
2013
2.2(12) ms
α
195 At
13/2+#
200 Fr
87
113
200.00658(3)
1995
47.5(28) ms
α
196 At
(3+)
200m1 Fr[ n 7]
50(60) keV
2014
190(120) ms
α
196 At
10−#
200m2 Fr
150(50)# keV
(2014)[ n 8]
790(360) ns
201 Fr
87
114
201.003852(10)
1980
62.8(19) ms
α
197 At
9/2−
201m1 Fr
129(10) keV
2005
24(6) ms
α
197 At
1/2+
201m2 Fr
289.5(4) keV
2014
720(40) ns
IT
201 Fr
13/2+
202 Fr
87
115
202.003330(6)
1980
372(12) ms
α
198 At
3+
202m Fr
257(6) keV
1992
286(13) ms
α
198 At
10−
IT (?%)
202 Fr
203 Fr
87
116
203.000941(7)
1967
550(10) ms
α
199 At
9/2−
203m1 Fr
361(6) keV
2013
43(4) ms
IT (80%)
203 Fr
1/2+
α (20%)
199 At
203m2 Fr
426.0(10) keV
2013
370(50) ns
IT
203 Fr
13/2+
204 Fr
87
117
204.000652(26)
1964
1.75(26) s
α (96%)
200 At
3+
β+ (4%)
204 Rn
204m1 Fr
50(4) keV
1967
2.41(19) s
α (90%)
200 At
7+
β+ (10%)
204 Rn
204m2 Fr
326(4) keV
1992
1.65(15) s
α (53%)
200 At
10−
IT (47%)
204 Fr
205 Fr
87
118
204.998594(8)
1964
3.90(7) s
α (98.5%)
201 At
9/2−
β+ (1.5%)
205 Rn
205m1 Fr
544.0(10) keV
2012
80(20) ns
IT
205 Fr
13/2+
205m2 Fr
609(6) keV
2012
1.15(4) ms
IT
203 Fr
(1/2+)
206 Fr
87
119
205.998661(30)
1964
~16 s
α (88.4%)
202 At
3+
β+ (11.6%)
206 Rn
206m1 Fr
200(40) keV
1981
~16 s
α (84.7%)
202 At
7+
β+ (?%)
206 Rn
IT (?%)
206 Fr
206m2 Fr
730(40) keV
1981
700(100) ms
IT (87%)
206 Fr
10−
α (13%)
202 At
207 Fr
87
120
206.996941(19)
1964
14.8(1) s
α (95%)
203 At
9/2−
β+ (5%)
207 Rn
208 Fr
87
121
207.997139(13)
1964
59.1(3) s
α (89%)
204 At
7+
β+ (11%)
208 Rn
208m Fr
826.3(5) keV
2009
432(11) ns
IT
208 Fr
10−
209 Fr
87
122
208.995940(12)
1964
50.5(7) s
α (89%)
205 At
9/2−
β+ (11%)
209 Rn
209m Fr
4659.8(7) keV
2006
420(18) ns
IT
209 Fr
45/2−
210 Fr
87
123
209.996411(14)
1964
3.18(6) min
α (71%)
206 At
6+
β+ (29%)
210 Rn
210m Fr
4417.2(10) keV
2016
475(6) ns
IT
210 Fr
(23)+
211 Fr
87
124
210.995555(13)
1964
3.10(2) min
α (87%)
207 At
9/2−
β+ (13%)
211 Rn
211m1 Fr
2423.16(24) keV
1986
146(14) ns
IT
211 Fr
29/2+
211m2 Fr
4657.3(4) keV
1986
124.5(12) ns
IT
211 Fr
45/2−
212 Fr
87
125
211.996225(9)
1950
20.0(6) min
β+ (57%)
212 Rn
5+
α (43%)
208 At
212m1 Fr
1551.4(3) keV
1990
31.9(7) μs
IT
212 Fr
11+
212m2 Fr
2492.2(4) keV
1977
604(28) ns
IT
212 Fr
15−
212m3 Fr
5854.7(6) keV
1986
312(21) ns
IT
212 Fr
27−
212m4 Fr
8533.4(11) keV
1990
23.6(21) μs
IT
212 Fr
34+#
213 Fr
87
126
212.996184(5)
1964
34.14(6) s
α (99.44%)
209 At
9/2−
β+ (0.56%)
213 Rn
213m1 Fr
1590.41(18) keV
1976
505(14) ns
IT
213 Fr
21/2−
213m2 Fr
2537.62(23) keV
1976
238(6) ns
IT
213 Fr
29/2+
213m3 Fr
8094.8(7) keV
1989
3.1(2) μs
IT
213 Fr
(65/2−)
214 Fr
87
127
213.998971(9)
1966
5.51(13) ms
α
210 At
(1−)
214m1 Fr
121(5) keV
1968
3.35(5) ms
α
210 At
(8−)
214m2 Fr
638(5) keV
1994
103(4) ns
IT
214 Fr
(11+)
214m3 Fr
6577(100)# keV
1994
108(7) ns
IT
214 Fr
(33+)
215 Fr
87
128
215.000342(8)
1970
90(4) ns
α
211 At
9/2−
216 Fr
87
129
216.003190(4)
1970
700(20) ns
α
212 At
(1−)
216m Fr
219(6) keV
2007
850(30) ns
α
212m1 At[ 5]
(9−)
217 Fr
87
130
217.004632(7)
1968
22(5) μs
α
213 At
9/2−
218 Fr
87
131
218.007579(5)
1949
1.4(5) ms
α
214 At
1−
218m Fr
87(4) keV
1982
21.9(5) ms
α
214 At
(8−)
219 Fr
87
132
219.009251(7)
1948
22.5(17) ms
α
215 At
9/2−
220 Fr
87
133
220.012327(4)
1948
27.4(3) s
α (99.65%)
216 At
1+
β− (0.35%)
220 Ra
221 Fr
87
134
221.014254(5)
1947
4.801(5) min
α
217 At
5/2−
Trace[ n 9]
β− (0.0048%)
221 Ra
CD (8.8×10−11 %)[ n 10]
207 Tl14 C
222 Fr
87
135
222.017583(8)
1975
14.2(3) min
β− [ n 11]
222 Ra
2−
223 Fr
Actinium K
87
136
223.0197342(21)
1939
22.00(7) min
β−
223 Ra
3/2−
Trace[ n 12]
α (0.006%)
219 At
224 Fr
87
137
224.023348(12)
1969
3.33(10) min
β−
224 Ra
1−
225 Fr
87
138
225.025572(13)
1969
3.95(14) min
β−
225 Ra
3/2−
226 Fr
87
139
226.029545(7)
1969
48.5(7) s
β−
226 Ra
1−
227 Fr
87
140
227.031865(6)
1972
2.47(3) min
β−
227 Ra
1/2+
228 Fr
87
141
228.035839(7)
1972
38(1) s
β−
228 Ra
2−
228m Fr
1004(30) keV
(2008)[ n 13]
180(110) s
229 Fr
87
142
229.038291(5)
1975
50.2(4) s
β−
229 Ra
(1/2+)
230 Fr
87
143
230.042391(7)
1987
19.1(5) s
β−
230 Ra
2+#
231 Fr
87
144
231.045175(8)
1985
17.6(6) s
β−
231 Ra
(1/2+)
232 Fr
87
145
232.049461(15)
1990
5.5(6) s
β−
232 Ra
(5)
233 Fr
87
146
233.052518(21)
2010
900(100) ms
β−
233 Ra
1/2+#
This table header & footer:
↑ m Fr – Excited nuclear isomer .
↑ ( ) – Uncertainty (1σ ) is given in concise form in parentheses after the corresponding last digits.
↑ # – Atomic mass marked # : value and uncertainty derived not from purely experimental data, but at least partly from trends from the Mass Surface (TMS).
1 2 3 # – Values marked # are not purely derived from experimental data, but at least partly from trends of neighboring nuclides (TNN).
↑
Modes of decay:
↑ ( ) spin value – Indicates spin with weak assignment arguments.
1 2 Order of ground state and isomer is uncertain.
↑ Isomer had only been suggested, not included in discovery database
↑ Intermediate decay product of 237 Np
↑ The nuclide with the lowest atomic number known to undergo cluster decay
↑ Theoretically capable of α decay to 218 At with a partial half-life of ~1 d (branching ratio ~1%).[ 6]
↑ Intermediate decay product of 235 U
↑ Only published in a conference proceeding and not a refereed journal
References
1 2 3 4 Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF) . Chinese Physics C . 45 (3) 030001. doi :10.1088/1674-1137/abddae .
↑ Wang, Meng; Huang, W.J.; Kondev, F.G.; Audi, G.; Naimi, S. (2021). "The AME 2020 atomic mass evaluation (II). Tables, graphs and references*". Chinese Physics C . 45 (3) 030003. doi :10.1088/1674-1137/abddaf .
↑ FRIB Nuclear Data Group. "Discovery of Nuclides Project, Isotope Database" . doi :10.11578/frib/2279152 .
↑ FRIB Nuclear Data Group. "Discovery of Nuclides Project, Isomer Database" . doi :10.11578/frib/2572219 .
↑ "216 Fr α decay (850)" (PDF) . NNDC Chart of Nuclides.
↑ Hyde, E. K.; Ghiorso, A. (4 February 1950), Preparation of a New Isotope of Francium - Fr222 , California Univ., Berkeley (USA): Radiation Laboratory
Half-life, spin, and isomer data selected from the following sources.
Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties" , Nuclear Physics A , 729 : 3– 128, Bibcode :2003NuPhA.729....3A , doi :10.1016/j.nuclphysa.2003.11.001
National Nuclear Data Center . "NuDat 3.0 database" . Brookhaven National Laboratory .
Holden, Norman E. (2004). "11. Table of the Isotopes". In Lide, David R. (ed.). CRC Handbook of Chemistry and Physics (85th ed.). Boca Raton, Florida : CRC Press . ISBN 978-0-8493-0485-9 .
Group
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
Period
Hydrogen and alkali metals
Alkaline earth metals
Pnicto gens
Chal co gens
Halo gens
Noble gases
①
1
2
②
3
4
5
6
7
8
9
10
③
11
12
13
14
15
16
17
18
④
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
⑤
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
⑥
55
56
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
⑦
87
88
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
⑧
119
120
57
58
59
60
61
62
63
64
65
66
67
68
69
70
89
90
91
92
93
94
95
96
97
98
99
100
101
102